MATERIAL SAFETY DATA SHEET

 

Wausau Chemical Corporation, 2001 N. River Drive, Wausau, WI 54403

                                                                             Last Revision:               January 15, 2004

HMIS Hazard

4 – Extreme                  Health              2

3 – High                       Fire                  2

2 – Moderate               Reactivity         0

1 – Slight                      Other

0 - Least

 

 
Emergency       CHEMTREC              800-424-9300

Phones:            Wausau Chemical         715-842-2285

SECTION 1 - MATERIAL IDENTIFICATION

 

 

 
 

 

 


NAME:                        AROMATIC 100

SYNONYMS:             Light Aromatic Solvent Naphtha

                                    Aromatic 100; SHFN

MANUFACTURERS: Citgo Petroleum Corp

SECTION 2  - HAZARDOUS INGREDIENTS

 

 
 

 

 


HAZARDOUS CHEMICAL               CAS #             PERCENT       PEL/TWA        SARA III, SEC 313    

Light Aromatic Solvent Naphtha           64742-95-6     100%               100 ppm                      NO

Xylenes                                                1330-20-7         0-3%             150 ppm                      YES

Cumene                                                92-82-8             0-3%               50 ppm                      YES

n-Propylbenzene                                   103-65-1           1-10%           NA                              NO

Trimethylbenzenes                                25551-13-7     30-65%           25 ppm                        NO

1,2,4-Trimethylbenzenes                       95-63-6           10-45%           100 ppm                      YES

Ethylmethylbenzenes                             25550-14-5     10.25%            NA                              NO

SECTION 3 – CHEMICAL AND PHYSICAL PROPERTIES

 
 

 

 


Appearance:           Clear, colorless liquid                      Boiling Point (oF):                                 227-356oF

Odor:                     Sweet, aromatic hydrocarbon         Freezing Point (oF):                               -13 to 55oF

pH:                         NA                                                            Specific Gravity (H2O=1 @ 70oF):       0.87

Water solubility:            Slight                                        Vapor Pressure, mm Hg, 20oC:2           2.7 mm

Vapor Density (air=1)   :           3.5                               Volatile Organic (VOC) content:           100%

Evaporation Rate (Butyl Acetate = 1)                ND

SECTION 4 – FIRE AND EXPLOSION HAZARDS

 

 

 

 

 
 

 


Flash Point (Method):   107 - 113oF (TCC)     Flammable Limits: Lower          0.9%    Upper              7.0%

Auto Ignition Temperature:        650oF

Extinguishing Media:                 Foam, carbon dioxide, dry chemical, water fog or spray or inert gas. Never use water jet directly on fire because it may cause further spread.

Special Fire Fighting Procedures and Hazards:  Use of NIOSH-approved self-contained breathing apparatus is required. Vapors could travel along ground to source of ignition and cause flash back. Containers not properly cooled, could rupture in heat of fire.

Unusual Fire & Explosion Hazards:       Forms hazardous gases, smoke, carbon monoxide, carbon dioxide.

SECTION 5 – REACTIVITY INFORMATION

 

 

 

 
 

 


Stable:    X  Unstable:               Hazardous Polymerization:   Occurs:                 Does not Occur:           X

Conditions to Avoid:                 Keep away from high heat, strong acids and strong oxidizing conditions.

Materials to Avoid:                   Strong acids, alkalies, and oxidizers such as liquid chlorine, hydrogen peroxide, and oxygen.

Decomposition Products:          None-known.


Aromatic 100                                                                                                                                      Page 2

SECTION 6 – HEALTH HAZARDS – PROTECTIVE MEASURES  – FIRST AID

 
 

 


Carcinogen:      No

EYES:              Mild eye irritant. Symptoms may include stinging, watering, redness and swelling. Flush with water for 15 minutes while holding eyelids apart in the event of contact. Get medical attention if symptoms occur. Use chemical goggles when handling this product.

SKIN:              Can cause skin irritation on repeated or prolonged contact. Symptoms may include redness, itching, drying, swelling, blistering, cracking, and severe tissue damage. Wash thoroughly with soap and water, while removing contaminated clothing and shoes. Can be absorbed through the skin and produce central nervous system (CNS) depression. Use neoprene or rubber gloves and apron when handling this product. Get medical attention if symptoms persist.

INHALATION:           Excessive concentrations of mist or vapors can cause irritation of the respiratory system as well as euphoria, excitation or giddiness, headache, nausea, vomiting abdominal pain, loss of appetite and CNS depression at high concentrations, including sudden death from cardiac arrest. Provide adequate ventilation. Remove victim to fresh air immediately. If not breathing, perform artificial respiration. Get immediate medical attention.

INGESTION:  Can cause irritation of the mucous membranes. Readily absorbed by the stomach and intestinal tract with nausea, vomiting, dizziness, drowsiness, loss of consciousness, delirium and CNS effects. DO NOT induce vomiting. If spontaneous vomiting occurs, place victims head below knees to avoid aspiration to the lungs. Get immediate medical attention.

IN ALL CASES:          GET PROMPT MEDICAL ATTENTION IF ADVERSE EFFECTS PERSIST

PRIMARY ROUTES OF ENTRY:      Skin, eyes, inhalation, ingestion

HYGIENE:      Wash hands and face before eating or drinking. Wash soiled clothing before wearing again if contact occurs.

SECTION 7 – PRECAUTIONS FOR SAFE HANDLING, STORAGE AND USE

 
 

 

 


SPILLS AND LEAKS:            A spill or leak can cause an immediate fire/explosion hazard. Eliminate ignition sources. Contain to prevent loss to the environment. Collect excess material. Prevent from entering sewers or waterways.

 

STORAGE AND HANDLING:           Keep containers tightly closed. Store away from heat or combustion sources. Ground containers and equipment containing this material. Store in well-ventilated area.

 

WASTE DISPOSAL:              Follow recommendations of local, state and federal regulations.

 

EMPTY CONTAINERS:        Tighten closures. Keep away from ignition sources. Empty containers contain residues that can ignite with explosive force. Send to a recycling firm or return to Wausau Chemical Corporation.


SECTION 8 – REGULATORY INFORMATION

 

 

 

DOT SHIPPING DESCRIPTION:      Petroleum Distillate, N.O.S., (Naphtha Solvent), 3, UN1268, PG III

LABEL REQUIRED                            NONE

The information contained herein is given in good faith, but no warranty, representation, inducement or license of any kind is made, except that the information is accurate to the best of Wausau Chemical Corporation’s knowledge, or is obtained from sources believed by Wausau Chemical Corporation to be reliable and accurate. Wausau Chemical Corporation does not assume any legal responsibility for use or reliance upon the information being furnished. Customers are encouraged to conduct their own tests. Before using any product, read the container label directions as well as the Material Safety Data Sheet.

 
 

 

 

 

 

 


ND – Not Determined              NA – Not Applicable               NE – Not Established

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