MATERIAL SAFETY DATA SHEET

 

Wausau Chemical Corporation, 2001 N. River Drive, Wausau, WI 54403

                                                                             Last Revision:              January 19, 2004

HMIS Hazard 4 – Extreme                  Health              1 3 – High                       Fire                  2 2 – Moderate               Reactivity         0 1 – Slight                      Other 0 - Least

Emergency       CHEMTREC              800-424-9300

Phones:            Wausau Chemical         715-842-2285

SECTION 1 - MATERIAL IDENTIFICATION

 

 

 

NAME:                        CITRI-PLUS #101

SYNONYMS:            

SECTION 2  - HAZARDOUS INGREDIENTS

 

 

 

HAZARDOUS CHEMICAL               CAS #             PERCENT       PEL/TWA        SARA III, SEC 313    

1-Methyl-4-(1-Methylethenyl)-Cyclohexene

                                                            5989-27-5       100%                  NE                            NO

 

 

SECTION 3 – CHEMICAL AND PHYSICAL PROPERTIES

 

 

 

Appearance:           Clear, light yellow liquid                  Boiling Point (^oF):                                 310 ^oF

Odor:                     Citrus orange                                  Freezing Point (^oF):                               ND

pH:                         NA                                                            Specific Gravity (H₂O=1 @ 70^oF):       0.830

Water solubility:            Miscible                                   Vapor Pressure, mm Hg, 20^oC: ND

Vapor Density (air=1)   :           ND                              Volatile Organic (VOC) content:           96%

Evaporation Rate (Butyl Acetate = 1)                ND

 

SECTION 4 – FIRE AND EXPLOSION HAZARDS

 

 

Flash Point (Method):               115 ^oF              Flammable Limits: Lower          0.7%    Upper              6.1%

Auto Ignition Temperature:        NE

Extinguishing Media:                 Carbon dioxide, foam and dry chemical.

 

Special Fire Fighting Procedures and Hazards:  SCBA recommended. Do not use water. Handle as if an oil fire. Wear self-contained breathing apparatus.

 

Unusual Fire & Explosion Hazards:                   Improperly stored soaked rags can spontaneously combust.

 

SECTION 5 – REACTIVITY INFORMATION

 

 

Stable:    X  Unstable:               Hazardous Polymerization:   Occurs:                 Does not Occur:           X

 

Conditions to Avoid:                 Excessive heat. Ignition sources.

 

Materials to Avoid:                   Strong oxidizers and acidic agents.

 

Decomposition Products:          Fire will create carbon dioxide and carbon monoxide.

Citri-Plus #101                                                                                                                                   Page 2

SECTION 6 – HEALTH HAZARDS – PROTECTIVE MEASURES  – FIRST AID

 

 

Carcinogen:      No

 

EYES:              Mild eye irritant. Use chemical goggles when handling this product. In the event of contact flush with water for 15 minutes. Get medical attention if symptoms develop.

 

SKIN:              Can cause skin irritation on repeated or prolonged contact. Use neoprene or rubber gloves and apron when handling this product. In the event of contact flush with water for 15 minutes. Remove contaminated clothing and wash before reuse. Get medical attention if symptoms develop.

 

INHALATION:           Mist or vapors can cause irritation of the respiratory system, coughing and headache.

 

INGESTION:              Harmful. May cause vomiting, headache as well as other medical problems. Do not induce vomiting. Rinse mouth with water, than drink a glass of water. Get immediate medical attention.

 

IN ALL CASES:          GET PROMPT MEDICAL ATTENTION IF ADVERSE EFFECTS PERSIST

 

PRIMARY ROUTES OF ENTRY:      Skin, eyes, inhalation, ingestion.

 

HYGIENE:      Wash hands and face before eating or drinking. Wash soiled clothing before wearing again if contact occurs.

SECTION 7 – PRECAUTIONS FOR SAFE HANDLING, STORAGE AND USE

 

 

 

SPILLS AND LEAKS:            Contain to prevent loss to the environment. Collect excess material. Flush residual material to a sanitary sewer.

 

STORAGE AND HANDLING:           Keep containers tightly closed. Store at ambient temperatures.

 

WASTE DISPOSAL:              Follow recommendations of local, state and federal regulations.

 

EMPTY CONTAINERS:        Send to a recycling center or return to Wausau Chemical Corporation.

 

SECTION 8 – REGULATORY INFORMATION

 

 

 

DOT SHIPPING DESCRIPTION:      Combustible Liquid, N.O.S., (Terpene Hydrocarbon), Combustible                                                      Liquid, NA1993, PG III

 

LABEL REQUIRED:                           NONE

The information contained herein is given in good faith, but no warranty, representation, inducement or license of any kind is made, except that the information is accurate to the best of Wausau Chemical Corporation’s knowledge, or is obtained from sources believed by Wausau Chemical Corporation to be reliable and accurate. Wausau Chemical Corporation does not assume any legal responsibility for use or reliance upon the information being furnished. Customers are encouraged to conduct their own tests. Before using any product, read the container label directions as well as the Material Safety Data Sheet.

 

 

 

 

 

 

ND – Not Determined              NA – Not Applicable               NE – Not Established