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4 Extreme Health 2 3 High Fire 3 2 Moderate Reactivity 0 1 Slight Other 0 - Least
Emergency CHEMTREC 800-424-9300
HMIS Hazard
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SECTION 1 - MATERIAL IDENTIFICATION
NAME: TOLUENE
SYNONYMS: Toluol; C7 Alkyl benzene;
Methylbenzene; Methylbenzol; Methaphene; Phenyl methane; Methacide
MANUFACTURER: Citgo Petroleum Corporation
SECTION 2 - HAZARDOUS
INGREDIENTS
Toluene 108-88-3 >99.9% 50 ppm YES
SECTION 3 CHEMICAL AND PHYSICAL PROPERTIES
Appearance: Clear, colorless liquid Boiling Point (oF): 231o 232oF
Odor: Sweet, pleasant aromatic Freezing Point (oF): ~-139oF
pH: NA Specific Gravity (H2O=1 @ 70oF): 0.872
Water solubility: Slight in cold water Vapor Pressure, mm Hg, 20oC: 23.8mm
Vapor Density (air=1): 3.18 Volatile Organic (VOC) content: 100%
Evaporation Rate (Butyl Acetate = 1) 1.9
SECTION 4 FIRE AND EXPLOSION HAZARDS
Flash Point (Method): 40oF Explosive Limits: Lower 1.2% Upper 7.1%
Auto Ignition Temperature: 896oF
Extinguishing Media: Water spray, dry chemical,
carbon dioxide or alcohol resistant foam, or nitrogen.
Special Fire Fighting Procedures and Hazards: Highly Flammable! Wear chemical protective clothing and positive pressure self-contained breathing apparatus. Approach upwind to avoid toxic vapors.
Unusual Fire & Explosion Hazards: Vapors can cause flash fire; also can travel along the ground to an ignition source and flash back. Vapor/air explosion may occur in confined areas. Containers not cooled properly may rupture in heat of fire.
SECTION 5 REACTIVITY INFORMATION
Stable: X Unstable: Hazardous Polymerization: Occurs: Does not Occur: X
Conditions to Avoid: Keep away from extreme heat, and strong oxidizers.
Materials to Avoid: Strong acids, alkalis, and oxidizers.
Decomposition Products: Not Known.
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SECTION 6 HEALTH HAZARDS PROTECTIVE MEASURES FIRST AID
Carcinogen: No
EYES: Mild to severe eye irritant. Could cause stinging, watering, redness, and swelling. Use chemical goggles when handling this product. In the event of contact flush with water for 15 minutes, while holding eyelids apart to ensure complete irrigation. Get medical attention if symptoms develop.
SKIN: Can cause mild to moderate skin irritation. Symptoms include redness, itching, and burning. Prolonged exposure may cause moderate dermatitis. This product may also be absorbed through the skin and cause depression of the central nervous system. Use neoprene or rubber gloves and apron when handling this product. In the event of contact wash with soap and water for 15 minutes while removing contaminated clothing. Seek medical attention if symptoms develop.
INHALATION: Breathing high concentrations of mist or vapors can cause irritation of the respiratory system, euphoria, excitation, headache, nausea, vomiting, abdominal pain, loss of appetite, fatigue, muscular weakness, staggering gait, depression of the central nervous system, and in some cases sudden death from cardiac arrest. Vapors can also reduce the oxygen content in air. Remove victim to fresh air. If victim is not breathing, perform artificial respiration. Get medical attention immediately.
INGESTION: Irritating to the mouth, esophagus and mucous membranes. Symptoms include a burning sensation of the mouth and esophagus, nausea, vomiting, dizziness, staggering gait, drowsiness, loss of consciousness, delirium, and could affect the central nervous system. Do Not induce vomiting or give anything by mouth. If vomiting occurs spontaneously, put victims head below their knees to avoid aspiration to lungs. Get immediate medical attention.
IN ALL CASES: GET PROMPT MEDICAL ATTENTION IF ADVERSE EFFECTS PERSIST
PRIMARY ROUTES OF ENTRY: Skin, eyes, inhalation, ingestion.
HYGIENE: Wash hands and face before eating or drinking. Wash soiled clothing before wearing again if contact occurs.
SECTION 7 PRECAUTIONS FOR SAFE HANDLING, STORAGE AND USE
SPILLS AND LEAKS: For small spills, contain to prevent loss to the environment. Absorb with dry material, collect, and transfer to waste container. For large spills, dike area to ensure complete collection. Absorb liquid for recycling or disposal. Do not flush into waterways or sewers.
STORAGE AND HANDLING: Keep containers tightly closed. Store in a cool, dry, well-ventilated area. Keep away from ignition sources.
WASTE DISPOSAL: Follow the recommendations of local, state and federal regulations.
EMPTY CONTAINERS: Replace and firmly tighten closures. Empty containers may contain product residue. Do not pressurize or expose containers to flame, sparks, or heat. Send to a recycling center or return to Wausau Chemical Corporation.
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SECTION 8 REGULATORY INFORMATION
DOT SHIPPING DESCRIPTION: Toluene, 3, UN1294, PG II
LABEL REQUIRED Flammable
The
information contained herein is given in good faith, but no warranty,
representation, inducement or license of any kind is made, except that the
information is accurate to the best of Wausau Chemical Corporations
knowledge, or is obtained from sources believed by Wausau Chemical
Corporation to be reliable and accurate. Wausau Chemical Corporation does
not assume any legal responsibility for use or reliance upon the
information being furnished. Customers are encouraged to conduct their own
tests. Before using any product, read the container label directions as
well as the Material Safety Data Sheet.
ND Not Determined NA Not Applicable NE Not Established